姓名

赵怀庆

学历/学位

博士研究生

职称/职务

教授

联系电话

电子邮箱

chm_zhaohq@ujn.edu.cn

实验室/办公室

逸夫科学楼B703

主讲课程

《有机化学》

科研方向：

研究领域：有机化学

研究方向：

1.有机方法学，如从事C-H键活化及官能团化的相关研究，惰性化学键的选择性断裂等。

2.有机功能分子的设计、合成及其应用研究。

研究经历：

2015年10月至今                 济南大学

2013年  1 月-2015年10月 中国科学院福建物质结构研究所

2010年11月-2012年11月 新加坡国立大学 Research Fellow

2010年  9  月-2010年11月 新加坡南洋理工大学 Research Fellow

科研成果及奖励（包括项目、专利、鉴定等）（2005年以来）：

主持项目：

1.济南大学高层次人才引进启动基金。

2.国家自然科学基金。

3.山东省自然科学基金。

教学成果与奖励（2005年以来）：

国家级大学生创新创业训练计划项目以及校级大学生创新创业训练计划项目多项。

多名本科生获得校级“优秀毕业论文”。

每年招收1-2名研究生，欢迎本科生加入实验室。

代表性论文（2005年以来）：

第一作者及通讯作者文章：

19. Rui   Wang, Hongyan Xu, Tingting Li, Cuncheng Li, Huaiqing Zhao* Iridium/Copper-Catalyzed   Oxidative C–H/O–H Annulation of Benzoic Acids with Saturated Ketones for   Accessing  Substituted Phthalides ChemCatChem 2020, 12, 5907-5911.

18. Baode   Shan, Baotao Kang, Mingyue Song, Rui Wang, Guozhu Chen, Cuncheng   Li, Huaiqing Zhao^a * Rhodium(III)‐Catalyzed Oxidative C(sp3)−H Alkenylation of 8‐Methylquinolines with Maleimides Under Aerobic Conditions Adv.   Synth. Catal. 2020, 362, 2541-2546.

17. Fuxu   Zhan, Wei Zhang, Huaiqing Zhao* Copper/Silver Cocatalyzed   Regioselective C5–H Functionalization of 8-Aminoquinoline Amides with   1,3-Dicarbonyl Compounds Synthesis 2020, 52, 1007-1014.

16. Xi Zhou, Hongyan Xu, Qiaodan Yang, Hua Chen,   Shoufeng Wang, and Huaiqing Zhao*Co(II)/Cu(II)-cocatalyzed   oxidative C–H/N–H functionalization of benzamides with ketones: a facile   route to isoindolin-1-ones Chem. Commun. 2019, 55,   8603-8606.

15. Ningxin Guo, Xiufen Liu, Hongyan Xu, Xi   Zhou and Huaiqing Zhao * A simple route towards the   synthesis of 1,4,5-trisubstituted 1,2,3-triazoles from primary amines and   1,3-dicarbonyl compounds under metal-free conditions Org. Biomol.   Chem., 2019, 17, 6148-6152.

14. Baode   Shan, Qing Miao, Rui Wang, Guohui Jia, Huaiqing Zhao* Cp*Rh(III)-catalyzed   C(sp³)−H alkenylation and arylation of 8-methylquinolines with quinones and thiophenes Catal. Commun.   2019, 112,

13. Wei   Zhang, Darun Yang, Wengui Wang, Shoufeng Wang, Huaiqing Zhao,* Iridium(III)-Catalyzed   Directed ortho-C(sp²)–H Amidation of Arenes with Sulfonamides Eur.   J. Org. Chem. 2018, 2071–2077.

12. Huaiqing   Zhao,* Xiangwen Xu, Wei Wu, Wei Zhang, Yunxian Zhang Urea-based   organocatalyst catalyzed direct C-H bond arylations of unactivated arenes Catal.   Commun. 2018, 111, 95–99.

11.   Huaiqing Zhao,* Xi Zhou, Bo   Li, Xiufeng Liu, Ningxin Guo, Zhengliang Lu, Shoufeng Wang   Rhodium(III)-Catalyzed C(sp³)-H Bond Aminocarbonylation with   Isocyanates J. Org. Chem. 2018, 83, 4153–4159.

10. Huaiqing   Zhao, Jie Shen, Changliang Ren, Wei Zeng, and Huaqiang Zeng* A Foldamer-Based   Organocatalyst for Direct Arylations of Unactivated Arenes Org. Lett. 2017,   19, 2190-2193.

9.   Quandi Jiang，Changlei Zhu，Huaiqing   Zhao*and Weiping Su*，Rh(III)-Catalyzed C−H Olefination of Benzoic Acids under Mild   Conditions using Oxygen as the Sole Oxidant，Chem.   -Asian J. 2016, 11,   356-359 (VIP paper and Front Cover).

8.   Changlei Zhu, Yuanfei Zhang,   Jian Kan, Huaiqing Zhao* and Weiping Su* Ambient-temperature ortho C−H   arylation of benzoic acids with aryl iodides with ligand-supported palladium   catalyst Org. Lett. 2015, 17, 3418-3421.

7. Huaiqing Zhao, Shen Sheng, Yunhan   Hong, and Huaqiang Zeng* Proton Gradient-Induced Water Transport Mediated by   Water Wires Inside Narrow Aquapores of Aquafoldamer Molecules J. Am.   Chem. Soc. 2014, 136, 14270-14276.

6. Huaiqing   Zhao, Yaping Shang, Weiping Su* Rhodium(III)-Catalyzed Intermolecular N‑Chelator-Directed   Aromatic C-H Amidation with Amides Org. Lett. 2013, 15,   5106-5109.

5.   Huaiqing Zhao, Jie Shen, Juanjuan Guo, Ruijuan Ye, and Huaqiang Zeng* A   macrocyclic aromatic pyridone pentamer as a highly efficient organocatalyst   for the direct arylations of unactivated arenes Chem. Commun. 2013,   49, 2323-2325.

4.   Huaiqing Zhao, Wei Qiang Ong, Feng Zhou, Xiao Fang, Xueyuan Chen, Sam F.   Y. Li, Haibi Su, Nam-Joon Cho, and Huaqiang Zeng* Chiral crystallization of   aromatic helical foldamers via complementarities in shape and end   functionalities Chem. Sci. 2012, 3, 2042-2046.

3. Huaiqing   Zhao, Wei Qiang Ong, Xiao Fang, Feng Zhou, Meng Ni Hii, Sam Fong Yau Li,   Haibin Su and Zeng Huaqiang* Synthesis, structural investigation and   computational modelling of water-binding aquafoldamers Org. Biomol.   Chem. 2012, 10, 1172 – 1180 (Front Cover and Hot   Paper).

2. Huaiqing   Zhao, Ye Wei, Jing Xu, Jian Kan, Weiping Su,* and Maochun Hong Pd/PR₃   Catalyzed Cross-Coupling of Aromatic Carboxylic Acids with   Electron-deficient Polyfluoroarenes via Combination of Decarboxylation and sp²   C-H bond activation J. Org. Chem. 2011, 76,   882-893.

1. Huaiqing   Zhao, Min Wang, Weiping Su,* and Maochun Hong Copper-Catalyzed   Intermolecular Amination of Acidic Aryl C–H Bonds with Primary Aromatic   Amines Adv. Synth. Catal. 2010, 352, 1301-1306.